Originally posted by Garguy
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When flint (silica) is dissolved over many tens of thousands of years the surface becomes dissolved in a process called disaggregation; which leaves the surface looking like honeycombe (at least under a microscope :-) ). Chemical compounds may invade those pores and it is what we are seeing here.
I have a large collection of heat-treated flint, from a later period, so I am familiar with the difference. You are right that heat does alter the colour of flints and cherts, but that is inherent colour change. As an example, this long-blade bipolar core has been heat-treated. I have some from the same site that suffered modern damage and the colour is inherent; although the colours cahnge from the cortex, near surface and deeper into the flint.
In contrast, the large nodule is from glacial gravels and I have broken it open to show how the internal flint is still its original dark colour
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